1.14.18.11: plant 4alpha-monomethylsterol monooxygenase

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For detailed information about plant 4alpha-monomethylsterol monooxygenase, go to the full flat file.

Reaction

Synonyms

4alpha-methyl oxidase, 4alpha-methyl-DELTA7-sterol-4alpha-methyl-oxidase, 4alpha-methylsterol C4 oxidase, 4alpha-methylsterol-4alpha-methyl-oxidase, 4alpha-MSO, methylsterol monooxygenase 2, SMO2, SMO2-1, SMO2-2, sterol-4alpha-methyl oxidase 2

ECTree

     1 Oxidoreductases

         1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

             1.14.18 With another compound as one donor, and incorporation of one atom of oxygen into the other donor

                1.14.18.11 plant 4alpha-monomethylsterol monooxygenase

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5	AA Sequence
5	Cloned(Commentary)
8	Cofactor
3	General Information
2	IC50 Value
9	Inhibitors
2	Localization
3	Metals/Ions
5	Natural Substrates/ Products (Substrates)
10	Organism
5	Pathway
1	Protein Variants
4	Reaction
10	Reference
3	Source Tissue
26	Substrates and Products (Substrate)
3	Subunits
21	Synonyms
1	Systematic Name

Reaction

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Reaction on EC 1.14.18.11 - plant 4alpha-monomethylsterol monooxygenase

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REACTION

REACTION DIAGRAM

COMMENTARY

ORGANISM

UNIPROT

LITERATURE

24-methylidenelophenol + 2 ferrocytochrome b5 + O2 + 2 H+ = 4alpha-(hydroxymethyl)ergosta-7,24(241)-dien-3beta-ol + 2 ferricytochrome b5 + H2O

(1a)

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24-methylidenelophenol + 6 ferrocytochrome b5 + 3 O2 + 6 H+ = 3beta-hydroxyergosta-7,24(241)-dien-4alpha-carboxylate + 6 ferricytochrome b5 + 4 H2O

overall reaction

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4alpha-(hydroxymethyl)ergosta-7,24(241)-dien-3beta-ol + 2 ferrocytochrome b5 + O2 + 2 H+ = 4alpha-formylergosta-7,24(241)-dien-3beta-ol + 2 ferricytochrome b5 + 2 H2O

(1b)

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4alpha-formylergosta-7,24(241)-dien-3beta-ol + 2 ferrocytochrome b5 + O2 + 2 H+ = 3beta-hydroxyergosta-7,24(241)-dien-4alpha-carboxylate + 2 ferricytochrome b5 + H2O

(1c)

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