1.14.19.64: (S)-stylopine synthase

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Word Map on EC 1.14.19.64

1.14.19.64

californica

eschscholzia

sanguinarine

coptis

berberine

benzophenanthridine

japonica

s-tetrahydrocolumbamine

s-scoulerine

mexicana

isoquinoline

cyp80b1

argemone

poppy

benzylisoquinoline

majus

chelidonium

6-hydroxylase

protopine

papaveraceae

pharmacology

synthesis

Reaction

+ 2 H2O

Synonyms

(S)-cheilanthifoline oxidase (methylenedioxy-bridge-forming), CYP719A13, CYP719A2, CYP719A2/A3, CYP719A3, EC 1.1.3.32, EC 1.14.21.1, methylenedioxy bridge-forming enzyme, stylopine synthase, synthase, (S)-stylopine

ECTree

1 Oxidoreductases

1.14 Acting on paired donors, with incorporation or reduction of molecular oxygen

1.14.19 With oxidation of a pair of donors resulting in the reduction of O₂ to two molecules of water

1.14.19.64 (S)-stylopine synthase

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1	Molecular Weight [Da]
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10	Source Tissue
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Systematic Name on EC 1.14.19.64 - (S)-stylopine synthase

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(S)-cheilanthifoline,[reduced NADPH-hemoprotein reductase]:oxygen oxidoreductase (methylenedioxy-bridge-forming)

A cytochrome P-450 (heme-thiolate) protein catalysing an oxidative reaction that does not incorporate oxygen into the product. Forms the second methylenedioxy bridge of the protoberberine alkaloid stylopine from oxidative ring closure of adjacent phenolic and methoxy groups of cheilanthifoline.