1.14.19.64: (S)-stylopine synthase
This is an abbreviated version!
For detailed information about (S)-stylopine synthase, go to the full flat file.
Word Map on EC 1.14.19.64
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1.14.19.64
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californica
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eschscholzia
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sanguinarine
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coptis
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berberine
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benzophenanthridine
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japonica
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s-tetrahydrocolumbamine
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s-scoulerine
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mexicana
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isoquinoline
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cyp80b1
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argemone
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poppy
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benzylisoquinoline
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majus
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chelidonium
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6-hydroxylase
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protopine
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papaveraceae
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pharmacology
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synthesis
- 1.14.19.64
- californica
-
eschscholzia
- sanguinarine
- coptis
- berberine
-
benzophenanthridine
- japonica
-
s-tetrahydrocolumbamine
-
s-scoulerine
- mexicana
- isoquinoline
- cyp80b1
-
argemone
- poppy
-
benzylisoquinoline
- majus
-
chelidonium
-
6-hydroxylase
- protopine
- papaveraceae
- pharmacology
- synthesis
Reaction
Synonyms
(S)-cheilanthifoline oxidase (methylenedioxy-bridge-forming), CYP719A13, CYP719A2, CYP719A2/A3, CYP719A3, EC 1.1.3.32, EC 1.14.21.1, methylenedioxy bridge-forming enzyme, stylopine synthase, synthase, (S)-stylopine
ECTree
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Natural Substrates Products
Natural Substrates Products on EC 1.14.19.64 - (S)-stylopine synthase
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REACTION DIAGRAM
(R,S)-cheilanthifoline + [reduced NADPH-hemoprotein reductase] + O2
(R,S)-stylopine + [oxidized NADPH-hemoprotein reductase] + H2O
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(S)-cheilanthifoline + [reduced NADPH-hemoprotein reductase] + O2
(S)-stylopine + [oxidized NADPH-hemoprotein reductase] + 2 H2O
the enzyme is involved in biosynthesis of stylopine
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(S)-cheilanthifoline + [reduced NADPH-hemoprotein reductase] + O2
(S)-stylopine + [oxidized NADPH-hemoprotein reductase] + H2O
(S)-tetrahydrocolumbamine + [reduced NADPH-hemoprotein reductase] + O2
(S)-tetrahydroberberine + [oxidized NADPH-hemoprotein reductase] + H2O
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additional information
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the methylenedioxy bridge-forming enzyme is involved in stylopine biosynthesis in Eschscholzia californica, biosynthetic pathway for a variety of isoquinoline alkaloids, overview
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(S)-stylopine + [oxidized NADPH-hemoprotein reductase] + H2O
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(S)-cheilanthifoline + [reduced NADPH-hemoprotein reductase] + O2
(S)-stylopine + [oxidized NADPH-hemoprotein reductase] + H2O
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enzyme is induced 20 h after challenging the cell suspension culture with elicitor
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(S)-cheilanthifoline + [reduced NADPH-hemoprotein reductase] + O2
(S)-stylopine + [oxidized NADPH-hemoprotein reductase] + H2O
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stylopine biosynthesis involves the sequential formation of two methylenedioxy bridges, (S)-stylopine is an important intermediate in the biosynthesis of benzophenanthridine alkaloids, such as sanguinarine
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