1.14.14.95: germacrene A hydroxylase
This is an abbreviated version!
For detailed information about germacrene A hydroxylase, go to the full flat file.
Word Map on EC 1.14.14.95
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1.14.14.95
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sesquiterpene
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lactone
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costunolide
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asteraceae
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synthases
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terpene
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cos
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feverfew
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chicory
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parthenolide
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1-deoxy-d-xylulose-5-phosphate
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spinosa
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reductoisomerase
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tanacetum
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benthamiana
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amorphadiene
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artemisinic
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+-germacrene
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parthenium
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sunflower
- 1.14.14.95
-
sesquiterpene
- lactone
- costunolide
- asteraceae
- synthases
-
terpene
- cos
- feverfew
- chicory
- parthenolide
- 1-deoxy-d-xylulose-5-phosphate
- spinosa
- reductoisomerase
-
tanacetum
- benthamiana
-
amorphadiene
-
artemisinic
-
+-germacrene
- parthenium
- sunflower
Reaction
+ 3 [reduced NADPH-hemoprotein reductase] + 3 O2 = + 3 [oxidized NADPH-hemoprotein reductase] + 4 H2O
Synonyms
(+)-germacrene A hydroxylase, EC 1.1.1.314, EC 1.14.13.123, GAO, germacrene A oxidase, NADP+-dependent sesquiterpenoid dehydrogenase
ECTree
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Substrates Products
Substrates Products on EC 1.14.14.95 - germacrene A hydroxylase
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REACTION DIAGRAM
(+)-germacrene A + [reduced NADPH-hemoprotein reductase] + O2
germacra-1(10),4,11(13)-trien-12-ol + [oxidized NADPH-hemoprotein reductase] + H2O
beta-elemene + [reduced NADPH-hemoprotein reductase] + O2
elema-1,3,11(13)-trien-12-ol + [oxidized NADPH-hemoprotein reductase] + H2O
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the amount of (+)-beta-elemene hydroxylated is 2times less than that of (-)-beta-elemene
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-
?
germacra-1(10),4,11(13)-trien-12-ol + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
germacra-1(10),4,11(13)-trien-12-oate + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O
germacrene A + [reduced NADPH-hemoprotein reductase] + O2
12-hydroxygermacrene A + [oxidized NADPH-hemoprotein reductase] + H2O
germacra-1(10),4,11(13)-trien-12-ol + [oxidized NADPH-hemoprotein reductase] + H2O
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100% activity
germacra-1(10),4,11(13)-trien-12-ol is also named costol
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?
(+)-germacrene A + [reduced NADPH-hemoprotein reductase] + O2
germacra-1(10),4,11(13)-trien-12-ol + [oxidized NADPH-hemoprotein reductase] + H2O
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30% activity with NADH as compared to NADPH
germacra-1(10),4,11(13)-trien-12-ol is also named costol
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?
germacra-1(10),4,11(13)-trien-12-oate + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O
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-
-
-
?
germacra-1(10),4,11(13)-trien-12-ol + 2 O2 + 2 [reduced NADPH-hemoprotein reductase]
germacra-1(10),4,11(13)-trien-12-oate + 2 [oxidized NADPH-hemoprotein reductase] + 3 H2O
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-
-
?
12-hydroxygermacrene A + [oxidized NADPH-hemoprotein reductase] + H2O
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-
-
?
germacrene A + [reduced NADPH-hemoprotein reductase] + O2
12-hydroxygermacrene A + [oxidized NADPH-hemoprotein reductase] + H2O
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-
-
?
germacrene A + [reduced NADPH-hemoprotein reductase] + O2
12-hydroxygermacrene A + [oxidized NADPH-hemoprotein reductase] + H2O
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-
-
?
germacrene A + [reduced NADPH-hemoprotein reductase] + O2
12-hydroxygermacrene A + [oxidized NADPH-hemoprotein reductase] + H2O
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-
-
?
germacrene A + [reduced NADPH-hemoprotein reductase] + O2
12-hydroxygermacrene A + [oxidized NADPH-hemoprotein reductase] + H2O
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-
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?