1.14.14.162: flavanone 2-hydroxylase
This is an abbreviated version!
For detailed information about flavanone 2-hydroxylase, go to the full flat file.
Word Map on EC 1.14.14.162
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1.14.14.162
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flavone
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flavanones
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flavonoid
-
c-glycosides
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naringenin
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2-hydroxyflavanone
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sativa
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apigenin
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c-glycosylation
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eriodictyol
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2s-flavanone
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luteolin
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tricin
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grasses
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echinata
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glycyrrhiza
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b-ring
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today
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c-glucosyltransferase
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licorice
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chrysoeriol
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7,4'-dihydroxyflavone
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5'-hydroxylase
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o-glycosylate
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synthesis
- 1.14.14.162
- flavone
- flavanones
- flavonoid
-
c-glycosides
- naringenin
- 2-hydroxyflavanone
- sativa
- apigenin
-
c-glycosylation
- eriodictyol
-
2s-flavanone
- luteolin
- tricin
- grasses
- echinata
- glycyrrhiza
-
b-ring
-
today
-
c-glucosyltransferase
- licorice
- chrysoeriol
- 7,4'-dihydroxyflavone
-
5'-hydroxylase
-
o-glycosylate
- synthesis
Reaction
Synonyms
(2S)-flavanone 2-hydroxylase, CYP93G2, EC 1.14.13.87, EC 1.14.14.140, F2H, licodione synthase, liquiritigenin,[reduced NADPH-hemoprotein reductase]:oxygen oxidoreductase (licodione-forming), LS, More, Os06g01250, OsF2H
ECTree
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Reaction
Reaction on EC 1.14.14.162 - flavanone 2-hydroxylase
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a flavanone + [reduced NADPH-hemoprotein reductase] + O2 = a 2-hydroxyflavanone + [oxidized NADPH-hemoprotein reductase] + H2O
a flavanone + [reduced NADPH-hemoprotein reductase] + O2 = a 2-hydroxyflavanone + [oxidized NADPH-hemoprotein reductase] + H2O
a heme-thiolate protein, P-450, it probably forms 2-hydroxyliquiritigenin which spontaneously forms licodione, NADH can act instead of NADPH, but more slowly, reaction mechanism
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a flavanone + [reduced NADPH-hemoprotein reductase] + O2 = a 2-hydroxyflavanone + [oxidized NADPH-hemoprotein reductase] + H2O
mechanism, stereoselectivity