2.1.1.341: vanillate/3-O-methylgallate O-demethylase
This is an abbreviated version!
For detailed information about vanillate/3-O-methylgallate O-demethylase, go to the full flat file.
Word Map on EC 2.1.1.341
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2.1.1.341
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demethylation
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protocatechuate
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lignin
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4,5-cleavage
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catechol
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paucimobilis
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methanol
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sphingomonas
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4,5-dioxygenase
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h4folate
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sphingobium
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dioxygenase
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diols
- 2.1.1.341
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demethylation
- protocatechuate
- lignin
-
4,5-cleavage
- catechol
- paucimobilis
- methanol
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sphingomonas
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4,5-dioxygenase
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h4folate
- sphingobium
- dioxygenase
- diols
Reaction
Synonyms
DesA, LigM, Mtv, syringate O-demethylase, tetrahydrofolate-dependent O-demethylase, vanillate/3-O-methylgallate O-demethylase, vanillate/3MGA O-demethylase
ECTree
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Substrates Products
Substrates Products on EC 2.1.1.341 - vanillate/3-O-methylgallate O-demethylase
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REACTION DIAGRAM
dicamba + O2 + electron donor + tetrahydrofolate
? + oxidized electron donor + H2O + methyltetrahydrofolate
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titanium III citrate can act as electron donor, inducible three-component system consisting of MtvA, MtvB and MtvC, that catalyzes methyl transfer from vanillate to tetrahydrofolate
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-
?
gallate + 5-methyltetrahydrofolate
Q60FX1
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-
-
?
3-O-methylgallate + tetrahydrofolate
gallate + 5-methyltetrahydrofolate
Q7WST1
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0.4% of the activity with syringate
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?
3-O-methylgallate + tetrahydrofolate
gallate + 5-methyltetrahydrofolate
Q7WST1
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0.4% of the activity with syringate
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?
protocatechuate + 2 5-methyltetrahydrofolate
Q60FX1
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-
-
?
syringate + 2 tetrahydrofolate
protocatechuate + 2 5-methyltetrahydrofolate
Q60FX1
-
-
-
?
3-O-methylgallate + 5-methyltetrahydrofolate
Q7WST1
-
-
-
?
syringate + tetrahydrofolate
3-O-methylgallate + 5-methyltetrahydrofolate
Q7WST1
-
-
-
?
3,4-dihydroxybenzoate + 5-methyltetrahydrofolate
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-
-
-
?
vanillate + tetrahydrofolate
3,4-dihydroxybenzoate + 5-methyltetrahydrofolate
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titanium III citrate can act as electron donor, inducible three-component system consisting of MtvA, MtvB and MtvC, that catalyzes methyl transfer from vanillate to tetrahydrofolate
-
-
?
protocatechuate + 5-methyltetrahydrofolate
-
-
-
?
vanillate + tetrahydrofolate
protocatechuate + 5-methyltetrahydrofolate
Q60FX1
-
-
-
?
vanillate + tetrahydrofolate
protocatechuate + 5-methyltetrahydrofolate
Q60FX1
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procatechuic acid is 3,4-dihydroxybenzoate, procatechuic acid is 3,4-dihydroxybenzoate, which is further degraded via the procatechiuc acid 4,5-cleavage pathway
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?
vanillate + tetrahydrofolate
protocatechuate + 5-methyltetrahydrofolate
Q7WST1
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3% of the activity with syringate
-
?
vanillate + tetrahydrofolate
protocatechuate + 5-methyltetrahydrofolate
Q60FX1
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procatechuic acid is 3,4-dihydroxybenzoate, procatechuic acid is 3,4-dihydroxybenzoate, which is further degraded via the procatechiuc acid 4,5-cleavage pathway
-
?
vanillate + tetrahydrofolate
protocatechuate + 5-methyltetrahydrofolate
-
-
procatechuic acid is 3,4-dihydroxybenzoate, which is further degraded via the procatechiuc acid 4,5-cleavage pathway
-
?
vanillate + tetrahydrofolate
protocatechuate + 5-methyltetrahydrofolate
Q60FX1
-
-
-
?
vanillate + tetrahydrofolate
protocatechuate + 5-methyltetrahydrofolate
Q7WST1
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3% of the activity with syringate
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?
additional information
?
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Q60FX1
enzyme uses an ordered sequential mechanism
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-
?
additional information
?
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Q60FX1
syringate is no substrate
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-
?
additional information
?
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Q60FX1
no substrate: syringate
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-
?
additional information
?
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Q60FX1
no requirement for ATP
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-
?