1.14.13.208: benzoyl-CoA 2,3-epoxidase
This is an abbreviated version!
For detailed information about benzoyl-CoA 2,3-epoxidase, go to the full flat file.
Word Map on EC 1.14.13.208
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1.14.13.208
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evansii
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benzoate
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azoarcus
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epoxidation
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diiron
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boxc
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thioesters
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protocatechuate
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enoyl-coa
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homodimeric
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non-aromatic
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oxygenases
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coa-dependent
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succinyl-coa
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dihydrodiol
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iron-sulfur
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semialdehyde
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phenylacetyl-coa
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benzoate-induced
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diferric
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benzoate-coa
- 1.14.13.208
- evansii
- benzoate
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azoarcus
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epoxidation
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diiron
- boxc
- thioesters
- protocatechuate
- enoyl-coa
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homodimeric
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non-aromatic
- oxygenases
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coa-dependent
- succinyl-coa
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dihydrodiol
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iron-sulfur
- semialdehyde
- phenylacetyl-coa
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benzoate-induced
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diferric
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benzoate-coa
Reaction
Synonyms
benzoyl coenzyme A epoxidase, benzoyl-CoA 2,3-dioxygenase, benzoyl-CoA dioxygenase/reductase, benzoyl-CoA epoxidase, benzoyl-CoA oxygenase, benzoyl-coenzyme A epoxidase, BoxA, BoxA/BoxB system, BoxAB, BoxB, BoxBA, EC 1.14.12.21
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Natural Substrates Products
Natural Substrates Products on EC 1.14.13.208 - benzoyl-CoA 2,3-epoxidase
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REACTION DIAGRAM
benzoyl-CoA + NADPH + H+ + O2
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second step in aerobic benzoate metabolism, enzyme is induced by benzoate
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2,3-dihydro-2,3-dihydroxybenzoyl-CoA + NADP+
the enzyme is involved in aerobic benzoate metabolism in Azoarcus evansii
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benzoyl-CoA + NADPH + H+ + O2
2,3-dihydro-2,3-dihydroxybenzoyl-CoA + NADP+
the enzyme is involved in aerobic benzoate metabolism in Azoarcus evansii
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2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
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benzoyl-CoA + NADPH + H+ + O2
2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
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benzoyl-CoA + NADPH + H+ + O2
2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
Aromatoleum evansii KB 740
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benzoyl-CoA + NADPH + H+ + O2
2,3-epoxy-2,3-dihydrobenzoyl-CoA + NADP+ + H2O
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benzoyl-CoA epoxidase is a dinuclear iron enzyme that catalyzes the epoxidation reaction of the aromatic ring of benzoyl-CoA with chemo-, regio- and stereo-selectivity
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additional information
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benzoyl-CoA epoxidase is a dinuclear iron enzyme that catalyzes the epoxidation reaction of the aromatic ring of benzoyl-CoA with chemo-, regio- and stereo-selectivity. The enzyme may also catalyze the deoxygenation reaction of epoxide, suggesting a unique bifunctionality among the diiron enzymes
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additional information
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Aromatoleum evansii KB 740
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benzoyl-CoA epoxidase is a dinuclear iron enzyme that catalyzes the epoxidation reaction of the aromatic ring of benzoyl-CoA with chemo-, regio- and stereo-selectivity
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